Selecting pumps for chemical pumping can be challenging. The pumped medium's characteristics can lead users to a certain pump style that best fits a given application. This article examines certain issues for selecting pumps to be used in chemical pumping. With flocculants, polymers or reagents that have long polymer chains, certain types of pumps will not be a good fit. For example, a high-sheer pump will destroy the polymer chains. The net result will be an increased consumption of flocculants or polymers. This does not mean that the high-sheer pump will perform poorly, but it will damage the flocculants and cause the user to use significantly more flocculants or polymers. A low-sheer pump will not destroy the polymer chains and will allow the reagents to reach maximum effectiveness, resulting in less overall consumption.
This technology helped a facility save $20,000 in one year.
11/17/2015
Image 1. A rolling design peristaltic pump with only one hose compression per revolution and virtually no heat generation (Images and graphics courtesy of Flowrox)
Every process has variables that end users must consider to determine the most ideal pumping technology for their applications. A highly corrosive medium may require exotic alloys to survive chemical attack; however, certain types of pumps utilize Teflon or rubber components that may eliminate the need for exotic alloy housings and internal components such as titanium, Hastelloy C, Monel or others. The rubber or Teflon components are much less expensive than building complete pumps out of titanium or other exotic alloys. Also, diaphragm pumps and peristaltic pumps may be good alternatives to these other pump types.
Peristaltic pumps utilize rubber hoses and smaller diameter polymeric tubes that have extreme chemical resistance. The advantage is the pumps' hosing does not have to be made of exotic alloys. The rubber or polymeric hoses and tubes isolate the pump casing from the medium that is passing through the pump. These types of pumps are typically equipped with hose and tube leak-detection devices that alert the user when the internal elements have failed. The pump is then shut down and can be cleaned to prevent corrosion from taking place in the pump housing.
Table 1 shows a list of chemicals that may be pumped by pumps incorporating rubber as the wear components within the equipment.
Please note that high temperatures and high concentrations of the chemicals shown in Table 1 may cause some of the listed materials to become incorrect selections.
Table 1. Chemicals and their corresponding common wear compounds in pumps
Abrasion is another example of how certain pumps built with metal internals in direct contact with the medium may fail. There are two ways to combat severe abrasion: Make the internal components harder or make the internal wear components softer.
Figure 1. Typical shoe design pump that compresses the hose twice per revolution. This design can lead to heat generation that may shorten hose lifetime and increase pump operational costs.
Certain styles of centrifugal pumps have been successful with rubber coating impellers and all internal surfaces with rubber linings and coatings. This practice has worked well for many years in the mining industry. Also, peristaltic pumps, some rotary lobe pumps and progressive cavity pumps rely on rubber internal components as the wearing part.
Variables such as driving head or NPSHA may lead the consumer into different styles of pumps. Positive suction head is not typically a problem for most pumps. When driving head is weak or even negative, the style of pump may need to be varied. For example, certain pump styles may destroy themselves in applications where insufficient head is available. An example is a progressive cavity pump that runs dry and destroys the rotor and stator in minutes, if not seconds. Other pump styles such as peristaltic pumps have the ability to run dry at any time and can even perform suction lift duties when negative head exists.
When high pressure is required, certain pump styles such as multi-stage progressive cavity pumps, gear pumps and piston pumps may be the best fit. Other styles of pumps such as diaphragm pumps and peristaltic pumps will be limited to relatively low-pressure applications less than 240 pounds per square inch gauge (psig). Temperatures above 300 degrees F may completely eliminate pumps utilizing rubber components.
One example of a challenging medium involves pumping lime slurry or milk of lime. Milk of lime is a suspension of calcium hydroxide in water, and it is an effective alkali. Uses for industrial lime slurry are for municipal water treatment, pH adjustment in chemical production, metal precipitation, flue gas desulfurization and odor control. Lime slurry is typically not pumped at high pressures because of its abrasive nature. In many cases, the lime is pumped at approximately 30 to 40 percent solids and pressures of 150 psig or less. Often it is pumped at less than 75 psig.
Lime is a suspended solid that is jagged and abrasive, and it can scale internal components of pumps and piping systems. Lime is not the most abrasive application for a pump, but it ranks with many formidable opponents. The typical pressure at which it is pumped is manageable by many pumps, but the abrasiveness and the scale aspect can cause problems.
Table 2: The one-year operating cost of a 2.5-inch pump with a 4-inch shoe design pump.
Plant personnel investigated a rolling design peristaltic pump as a potential replacement.
The power plant was utilizing a 4-inch shoe design peristaltic pump to keep the revolutions per minute (rpm) low and limit the heat generation of this pump style. The plant decided to utilize a 2.5-inch rolling design peristaltic pump to do the work of the 4-inch shoe design pump in February 2008.
The purchase price of the 2.5-inch pump was about half of the 4-inch shoe design. Also, the 2.5-inch rolling design pump operated at almost four times the rpm of the 4-inch shoe design but produced tremendous operational savings as well. The City of Hamilton saved enough on operational costs that it could afford to purchase a new rolling design pump every year.